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Showing posts with label ozone depletion. Show all posts
Showing posts with label ozone depletion. Show all posts

Monday, June 23, 2008

Thinning of ozone layer – Effective checking would reduce global warming and enhance standard of environment:





Thinning of ozone layer – Effective checking would reduce global warming and enhance standard of environment:

For nearly a billion years, ozone molecules in the atmosphere have protected life on Earth from the effects of ultraviolet rays. It is a form of oxygen (O2). We all know that, oxygen we need to live and breathe. Normal oxygen consists of two oxygen atoms. Ozone, however, consists of three oxygen atoms and has the chemical formula O3. Ozone is formed when an electric spark is passed through oxygen. Over millions of years the action of sunlight and specifically the action of ultra violet light or UV on oxygen has created a layer of ozone high up in the atmosphere. This ozone layer resides in the stratosphere and surrounds the entire Earth. The action of UV light on this layer both destroys and creates ozone, a constant process going on silently. Thus, this process of absorbing portion of UV light, protecting us from the harmful exposure. In fact, UV-B radiation (280- to 315- nanometer (nm) wavelength) from the Sun is partially absorbed in this ozone layer. As a result, the amount of UV-B reaching Earth’s surface is greatly reduced. UV-A (315- to 400-nm wavelength) and other solar radiation are not strongly absorbed by the ozone layer. Human exposure to UV-B increases the risk of skin cancer, cataracts, and a suppressed immune system. UV-B exposure can also damage terrestrial plant life, single cell organisms, and aquatic ecosystems. In the past 60 years or so human activities have contributed to the deterioration of the ozone layer to a great extent.

Mechanism of Ozone hole - The criticality of ozone layer can be understood from the fact that, only 10 or less of every million molecules of air is ozone. The majority of these ozone molecules reside in a layer between 10 and 40 kilometers above the surface of the Earth known as stratosphere. Each spring in the stratosphere over Antarctica (spring in the southern hemisphere is from September through November.), atmospheric ozone is rapidly destroyed by chemical processes. As winter arrives, a vortex of winds develops around the pole and isolates the polar stratosphere. When temperatures drop below -78°C, thin clouds form of ice, nitric acid, and sulfuric acid mixtures. Chemical reactions on the surfaces of ice crystals in the clouds release active forms of CFCs. Ozone depletion begins, and the ozone “hole” appears.

Over the course of two to three months, approximately 50% of the total column amount of ozone in the atmosphere disappears. At some levels, the losses approach 90%. This has come to be called the Antarctic ozone hole. In spring, temperatures begin to rise, the ice evaporates, and the ozone layer starts to recover.

Thus, ozone "hole" is a reduction in concentrations of ozone high above the earth in the stratosphere. The ozone hole is defined geographically as the area wherein the total ozone amount is less than 220 Dobson Units. The ozone hole has steadily grown in size and length of existence over the past two and half decades. Now, the size of ozone hole over Antarctica is estimated to be about 30 million sq. km.

It has been observed that, man-made chlorines, primarily chloroflourobcarbons (CFCs), contribute to the thinning of the ozone layer and allow larger quantities of harmful ultraviolet rays to reach the earth.

Effects of ozone layer depletion - UV-B (the higher energy UV radiation absorbed by ozone) are generally accepted to be a contributory factor to skin cancer. In addition, increased surface UV leads to increased troposphere ozone, which is a health risk to humans. The increased surface UV also represents an increase in the vitamin D synthetic capacity of the sunlight. The cancer preventive effects of vitamin D represent a possible beneficial effect of ozone depletion. In terms of health costs, the possible benefits of increased UV irradiance may outweigh the burden. In other words, a thinning of the ozone layer is the key factor in the greenhouse effect, and exposes life on Earth to excessive ultra violet radiation, which can increase skin cancer and cataracts, reduce immune-system responses,

As far as effect on plant is concerned, an increase of UV radiation would be expected to affect crops. A number of economically important species of plants, such as rice, depend on cyanbacteria residing on their roots for the retention of nitrogen. Cyanobacteria are sensitive to UV light and they would be affected by its increase. Thinning of the ozone layer also interfere with the photosynthetic process of plants,

Research has shown a widespread extinction of oceanic phytoplankton (a crucial source of food to aquatic life) is because of thinning of ozone layer. Researchers speculate that the extinction of plankton was caused by a significant weakening of the ozone layer at that time when the radiation from the supernova produced nitrogen oxides that catalyzed the destruction of ozone. Plankton is particularly susceptible to effects of UV light, and is vitally important to marine food webs.

Monday, March 3, 2008

Global warming and greenhouse gasses:


Global warming and greenhouse gasses:

The earth is surrounded by a cover of gasses as atmosphere. This atmosphere allows most of the light to pass through, which reaches the surface of earth. This light from sun is absorbed by the earth surface and converts into heat energy. This heat energy is re-emitted by the surface of the earth during night. Due excessive presence of some gasses in the atmosphere, this escape of heat from earth surface is prevented, resulting in heating of earth called ‘global warming’. The gasses which are responsible for causing global warming are called ‘greenhouse gasses’.

The harmful effects of presence of greenhouse gasses in atmosphere are global warming, climate change, ozone depletion, sea level rise, adverse effects on biodiversity etc. One way or another these adverse impacts are all directly or directly related to the presence of greenhouse gases in the atmosphere. A number of human activities, processes and consumptions produce waste gasses or greenhouse gasses that are harmful to the environment. They include:

(a) Fuel combustion
(b) Energy industries
(c) Manufacturing industries and construction
(d) Vehicle Transport and automobiles
(e) Fugitive emissions from fuels
(f) Burning of solid fuels
(g) Use of oil and natural gas
(h) Mineral products
(i) Chemical industry
(j) Metal production
(k) Production of halocarbons and sulfur hexafluoride
(l) Consumption of halocarbons and sulfur hexafluoride
(m) Solvent and other product use
(n) Enteric fermentation
(o) Manure management
(p) Rice cultivation
(q) Agricultural soils
( r) Prescribed burning of savannas
(s) Field burning of agricultural residues
(t) Solid waste disposal on land
(u) Wastewater handling
(v) Waste incineration

Much of these harmful gases are produced either naturally or by various human activities; which we should reduce. Brief description and effects of six important greenhouse gases are given below:

Carbon dioxide (CO2) - A naturally occurring gas produced by living organisms and fermentation. It is a normal component of the breath we exhale; it is hazardous in concentrated volumes. Large quantity of carbon dioxide is produced by the combustion of carbonaceous fuels. Carbon dioxide emissions from fuel burning, responsible for about 87 percent of global warming, have increased by about 27 percent since the industrial revolution.

Nitrogen oxides (NOx) – Nitrogen oxides are naturally occurring from microbial action in soil. NOx is also produced by fuel burning. Scientists say its production is increased by the use of nitrogen based fertilizers in agriculture, as well as by the use of catalytic converters in automobiles.

Methane (CH4) – Methane is a naturally occurring, in-flammable gas. Methane is produced by geological coal formations and by the decomposition of organic matters. Leading man-related sources of methane are landfills; livestock digestive processes and waste, especially ruminants (cud-chewing animals); and wetland rice cultivation.

Hydroflurocarbon gasses (HFCs) - Chlorofluorocarbons (CFC), the coolant, cleaning, and propellant gases were blacklisted internationally due to its ozone-eating characteristics. HFCs do contribute to global warming. Global warming potential of HFCs is 4,000 to 10,000 times that of CO2.

Perfluorocarbons (PFC), or perflurocompounds - Man-made replacement gases for CFCs but result also as a by-product of aluminium smelting. PFCs also used as a purging agent for semi-conductor manufacture and small amounts are produced during uranium enrichment processes. Global warming potential of Perfluorocarbons (PFC), or perflurocompounds is 6,000 to 10,000 that of CO2.

Sulfur hexafluoride (SF6) - Very low atmospheric concentration makes it an ideal test gas for gas concentration monitors. Principle uses: insulating material for high-voltage equipment like circuit breakers at utilities. Also used in water leak detection for cable cooling systems. SF6 is a man-made gas.